DNA duplex with phosphoryl guanidine moiety, Rp-diastereomer
Polymer type: polydeoxyribonucleotide
Total | 1H | 31P | |
---|---|---|---|
All | 73.9 % (153 of 207) | 72.9 % (137 of 188) | 84.2 % (16 of 19) |
Suger, PO4 | 80.9 % (123 of 152) | 80.5 % (107 of 133) | 84.2 % (16 of 19) |
Nucleobase | 54.5 % (30 of 55) | 54.5 % (30 of 55) | |
Aromatic | 76.3 % (29 of 38) | 76.3 % (29 of 38) | |
Methyl | 100.0 % (1 of 1) | 100.0 % (1 of 1) |
1. entity 1
CACGCCGCTG2. entity 2
CAGCGGCGXGSolvent system 100% D2O, Pressure 1 atm, Temperature 303.65 (±0.1) K, pH 7.2, Details 1 mM NA-H DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3'), 1 mM NA-H (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG), 10 mM sodium phosphate, 100 mM sodium chloride, 1 mM EDTA, 100% D2O
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
1 | DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3') | NA-H | 1 (±0.05) mM | |
2 | (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG) | NA-H | 1 (±0.05) mM | |
3 | sodium phosphate | natural abundance | 10 (±0.5) mM | |
4 | sodium chloride | natural abundance | 100 (±5.0) mM | |
5 | EDTA | natural abundance | 1 (±0.05) mM |
Solvent system 90% H2O/10% D2O, Pressure 1 atm, Temperature 303.65 (±0.1) K, pH 7.2, Details 1 mM NA-H DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3'), 1 mM NA-H (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG), 10 mM sodium phosphate, 100 mM sodium chloride, 1 mM EDTA, 90% H2O/10% D2O
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
6 | DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3') | NA-H | 1 (±0.05) mM | |
7 | (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG) | NA-H | 1 (±0.05) mM | |
8 | sodium phosphate | natural abundance | 10 (±0.5) mM | |
9 | sodium chloride | natural abundance | 100 (±5.0) mM | |
10 | EDTA | natural abundance | 1 (±0.05) mM |
Polymer type: polydeoxyribonucleotide
Total | 1H | 31P | |
---|---|---|---|
All | 50.2 % (208 of 414) | 51.1 % (192 of 376) | 42.1 % (16 of 38) |
Suger, PO4 | 47.7 % (145 of 304) | 48.5 % (129 of 266) | 42.1 % (16 of 38) |
Nucleobase | 57.3 % (63 of 110) | 57.3 % (63 of 110) | |
Aromatic | 60.5 % (46 of 76) | 60.5 % (46 of 76) | |
Methyl | 50.0 % (1 of 2) | 50.0 % (1 of 2) |
1. entity 1
CACGCCGCTG2. entity 2
CAGCGGCGXGSolvent system 100% D2O, Pressure 1 atm, Temperature 278.65 (±0.1) K, pH 7.2, Details 1 mM NA-H DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3'), 1 mM NA-H (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG), 10 mM sodium phosphate, 100 mM sodium chloride, 1 mM EDTA, 100% D2O
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
1 | DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3') | NA-H | 1 (±0.05) mM | |
2 | (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG) | NA-H | 1 (±0.05) mM | |
3 | sodium phosphate | natural abundance | 10 (±0.5) mM | |
4 | sodium chloride | natural abundance | 100 (±5.0) mM | |
5 | EDTA | natural abundance | 1 (±0.05) mM |
Solvent system 90% H2O/10% D2O, Pressure 1 atm, Temperature 278.65 (±0.1) K, pH 7.2, Details 1 mM NA-H DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3'), 1 mM NA-H (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG), 10 mM sodium phosphate, 100 mM sodium chloride, 1 mM EDTA, 90% H2O/10% D2O
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
6 | DNA (5'-D(*CP*AP*CP*GP*CP*CP*GP*CP*TP*G)-3') | NA-H | 1 (±0.05) mM | |
7 | (DC)(DA)(DG)(DC)(DG)(DG)(DC)(DG)(RGT)(DG) | NA-H | 1 (±0.05) mM | |
8 | sodium phosphate | natural abundance | 10 (±0.5) mM | |
9 | sodium chloride | natural abundance | 100 (±5.0) mM | |
10 | EDTA | natural abundance | 1 (±0.05) mM |