NMR structure of two cyclic oligonucleotides. A monomer-dimer equlilibrium between dumbbell and quadruplex structures.
ID | Type | Value order | Atom ID 1 | Atom ID 2 |
---|---|---|---|---|
1 | covalent | sing | 1:DT1:P | 1:DT8:O3' |
2 | covalent | sing | 1:DT1:P | 1:DT8:O3' |
Polymer type: polydeoxyribonucleotide
Total | 1H | |
---|---|---|
All | 86.4 % (70 of 81) | 86.4 % (70 of 81) |
Suger, PO4 | 100.0 % (56 of 56) | 100.0 % (56 of 56) |
Nucleobase | 56.0 % (14 of 25) | 56.0 % (14 of 25) |
Aromatic | 68.8 % (11 of 16) | 68.8 % (11 of 16) |
Methyl | 100.0 % (3 of 3) | 100.0 % (3 of 3) |
1. cyclic oligonucleotide
TGCTCGCTTemperature 293 (±1) K
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
1 | cyclic oligonucleotide | 5.0 mM | ||
2 | D2O | 100 % |
Polymer type: polydeoxyribonucleotide
Total | 1H | |
---|---|---|
All | 48.8 % (79 of 162) | 48.8 % (79 of 162) |
Suger, PO4 | 50.0 % (56 of 112) | 50.0 % (56 of 112) |
Nucleobase | 46.0 % (23 of 50) | 46.0 % (23 of 50) |
Aromatic | 50.0 % (16 of 32) | 50.0 % (16 of 32) |
Methyl | 50.0 % (3 of 6) | 50.0 % (3 of 6) |
1. cyclic oligonucleotide
TGCTCGCTTemperature 278 (±1) K
# | Name | Isotope labeling | Type | Concentration |
---|---|---|---|---|
3 | cyclic oligonucleotide | 5.0 mM | ||
4 | D2O | 0.0 ~ 0.0 % | ||
5 | H2O | 0.0 ~ 0.0 % |